UNEXPECTED SYNTHESIS OF A THIAZOLIC DERIV ATIVE RELATED TO DIDUROQUINONE

Authors
CROZET MP SABUCO JF BARREAU M VANELLE P
Citation
Mp. Crozet et al., UNEXPECTED SYNTHESIS OF A THIAZOLIC DERIV ATIVE RELATED TO DIDUROQUINONE, Comptes rendus de l'Academie des sciences. Serie 2, Mecanique, physique, chimie, sciences de l'univers, sciences de la terre, 318(2), 1994, pp. 185-190
Citations number
11
Categorie Soggetti
Multidisciplinary Sciences
Journal title
Comptes rendus de l'Academie des sciences. Serie 2, Mecanique, physique, chimie, sciences de l'univers, sciences de la terre → ACNP
ISSN journal
07644450
Volume
318
Issue
2
Year of publication
1994
Part
1
Pages
185 - 190
Database
ISI
SICI code
0764-4450(1994)318:2<185:USOATD>2.0.ZU;2-P
Abstract
thylthiazol-2-yl)-3,5,6-trimethyl-1,4-benzoquinone does not react eith er by C- or by O-alkylation with 2-nitropropane anion, but affords in 95% yield a single product related to diduroquinone, which results fro m the enolization of the quinone and cycloaddition between the interme diate product and the starting quinone.