Microscopically well-preserved leaf cuticles from four Upper Carbonife
rous pteridosperm (seed fern) genera have been analyzed using solid st
ate C-13 NMR and Curie-point pyrolysis. The chemical analyses reveal t
he presence of highly aliphatic macromolecules, comparable with cutan.
Cutan production is considered to be responsible for the preservation
of these plant structures, and hence for the abundance of well-preser
ved medullosan pteridosperm foliage in the Upper Carboniferous. Based
on a comparison of data from the literature, and these new results, it
is suggested that the resistant constituents of these cuticles may se
rve as an additional source for n-alkanes on diagenesis and catagenesi
s.