Cj. Wiebinga et Hjw. Debaar, DETERMINATION OF THE DISTRIBUTION OF DISSOLVED ORGANIC-CARBON IN THE INDIAN SECTOR OF THE SOUTHERN-OCEAN, Marine chemistry, 61(3-4), 1998, pp. 185-201
During France JGOFS campaign ANTARES 2 (R.V. Marion Dufresne), samples
were taken along a section of the 62 degrees E meridian from 49 degre
es to 66 degrees S. The high temperature catalytic oxidation (HTCO) me
thod was used to determine the concentration of dissolved organic carb
on (DOC). The analyses were conducted both on-board ship and after the
cruise in the laboratory. Collecting and storing acidified samples fo
r post-cruise analysis induced no significant differences. The use of
two separate but identical channels on the carbon analyzer increased t
he number of samples analysed per day and allowed independent monitori
ng of the instrument blank and the calibration of the detector respons
e. The mixed layer concentrations of organic carbon varied from about
52 mu M C in the Antarctic Divergence (64 degrees S) to about 63 mu M
C in the Polar Frontal Zone (49 degrees S). Vertical profiles showed a
slight, but significant, decrease in organic carbon below the mixed l
ayer, to about 42 mu M C below 2000 m across the transect. The homogen
eity and low concentration of organic carbon in deep water is consiste
nt with values recently reported for the equatorial Atlantic and Pacif
ic Ocean and supports the evidence for a constant deep water DOC conce
ntration. In addition, this provides a verification of the instrument
performance, thus validating observed DOC data trends and allowing a c
omparison with the 'modern' DOC literature. In general, the organic ca
rbon concentration in the mixed layer was lower than previously publis
hed data of the main ocean basins, which might -reflect the low chloro
phyll a concentration (< 0.5 mu g/l) encountered in this region. Along
the 62 degrees E meridian section, organic carbon showed a trend with
corresponding measurements of phytoplankton biomass and bacterial pro
duction, underlining the dependence of bacterial growth on a pool of '
freshly' produced DOG. Organic carbon was found to exhibit a weak inve
rse trend versus apparent oxygen utilization (AOU). This suggests that
only a small part of the oxygen consumption is due to the mineralisat
ion of DOG. (C) 1998 Elsevier Science B.V. All rights reserved.