COORDINATION-COMPOUNDS OF 4,2'-6',4''-TERPYRIDINE, [MCL2(4,2'-6',4''-TERPYRIDINE)], M = MN(II), CO(II), NI(II), CU(II) OR ZN(II) - CRYSTAL-STRUCTURE OF CATENA-POLY [(DICHLOROZINC)-MU-(4,2'-6',4''-TERPYRIDINE)]

Citation
M. Barquin et al., COORDINATION-COMPOUNDS OF 4,2'-6',4''-TERPYRIDINE, [MCL2(4,2'-6',4''-TERPYRIDINE)], M = MN(II), CO(II), NI(II), CU(II) OR ZN(II) - CRYSTAL-STRUCTURE OF CATENA-POLY [(DICHLOROZINC)-MU-(4,2'-6',4''-TERPYRIDINE)], Polyhedron, 17(13-14), 1998, pp. 2373-2378
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
ISSN journal
02775387
Volume
17
Issue
13-14
Year of publication
1998
Pages
2373 - 2378
Database
ISI
SICI code
0277-5387(1998)17:13-14<2373:CO4[>2.0.ZU;2-6
Abstract
MCl2 (4,2'-6',4 ''-terpyridine) compounds, where M = Mn(II), Co(II), N i(II),Cu(II) or Zn(II), have been synthesized and characterized by IR and electronic spectroscopy and susceptibility magnetic measurements. Crystalline structure of the Zn(II) complex has been determined by;X-r ay diffraction. The Zn(II) atom shows to be in a highly distorted tetr ahedral environment, defined by two Cl atoms and two N atoms of two li gand molecules, that act as bridges bound through the N atoms of the e xternal pyridine rings. The structure is made of chains that do not in teract among-them. (C) 1998 Elsevier Science ltd. All rights reserved.