COMPETITIVE DIFFUSION INTO 2 SINKS WITH A FINITE SURFACE-REACTION COEFFICIENT

Authors
Citation
G. Zoia et W. Strieder, COMPETITIVE DIFFUSION INTO 2 SINKS WITH A FINITE SURFACE-REACTION COEFFICIENT, The Journal of chemical physics, 108(8), 1998, pp. 3114-3118
Citations number
18
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
ISSN journal
00219606
Volume
108
Issue
8
Year of publication
1998
Pages
3114 - 3118
Database
ISI
SICI code
0021-9606(1998)108:8<3114:CDI2SW>2.0.ZU;2-M
Abstract
The asymptotic solution for the reaction rate of two identical spheric al sinks of radius p with a surface reaction rate coefficient k, place d in an infinite medium of diffusivity D, is presented for mid to high surface reaction rates, i.e., 1 < lambda(-1) = k rho/D < infinity. Th ese results are then discussed in the context of the complete kinetic problem from chemical, lambda(-1) approximate to 0.1, to diffusion con trol, lambda(-1) --> infinity. (C) 1998 American Institute of Physics.