ACID-BASE BEHAVIOR OF SOME ORTHOPALLADATED COMPLEXES

Authors
DIEZIZARRA JL GARCIA B IBEAS S LEAL JM GARCIAHERBOSA G MUNOZ A
Citation
Jl. Diezizarra et al., ACID-BASE BEHAVIOR OF SOME ORTHOPALLADATED COMPLEXES, Reactive & functional polymers, 36(3), 1998, pp. 227-233
Citations number
31
Categorie Soggetti
Polymer Sciences","Engineering, Chemical","Chemistry Applied
Journal title
Reactive & functional polymers → ACNP
ISSN journal
13815148
Volume
36
Issue
3
Year of publication
1998
Pages
227 - 233
Database
ISI
SICI code
1381-5148(1998)36:3<227:ABOSOC>2.0.ZU;2-#
Abstract
The acid dissociation constants of some orthopalladated complexes have been determined in 10% v/v DMSO/water mixed solvent. The positive cha rge is located on the Pd(II) atom; in basic medium the H atom on the l igand is partially released, which convert these complexes into zwitte rions, The ionization constants of the two overlapping equilibria of t he HA-dppm-AH complex were evaluated by application of the separation method. (C) 1998 Elsevier Science B.V. All rights reserved.