M. Zacchigna et al., HIGH-RESOLUTION RESONANT PHOTOEMISSION-STUDY OF THE 4F STATES IN A TYPICAL KONDO SYSTEM - CEPD3, EUROPEAN PHYSICAL JOURNAL B, 2(4), 1998, pp. 463-467
We exploited resonant photoemission at the Ce 4d --> 4f absorption edg
e to investigate the Ce 4f states in CePd3. High resolution spectra re
veal, near the Fermi level, the characteristic fine structure of inter
mediate valence Ce compounds. The spectral lineshape is consistent wit
h the typical ''Kondo'' character of CePd, but the prominent (f(0)) io
nization peak is found at the unusually low binding energy of 1 eV. We
briefly discuss the implications of these observations.