A study is made of the x-ray photoemission spectra of low-energy elect
rons (E-kin=0-30 eV) and its dependence on the way in which the potent
ials are applied to the entrance system of the analyzer. It is shown t
hat under certain experimental conditions the spectrum consists solely
of electrons emitted from the sample. The x-ray photoemission spectru
m of pure silver is found to have a fine structure, which disappears w
hen a surface layer of carbon or oxygen is deposited on the surface. T
he spectrum then cakes on the ''cascade'' form. A possible interpretat
ion of the fine structure is suggested in the framework of band theory
. (C) 1997 American institute of Physics.