Ej. Brandon et al., THE STRUCTURE OF SEVERAL SUPRAMOLECULAR MESO-TETRAARRYLPORPHINATOMANGANESE(III) TETRACYANOETHENIDE MAGNETS, Materials research bulletin, 1998, pp. 97-107
Supramolecular structures of several uniform ... D(+)A .D-+A .(-)D(+)A
.(-) (D: S = 2 Mporphyrin; A: S = 1/2 TCNE) coordination polymers, wi
th the [TCNE] .(-)trans-mu bonded to two Mn(III)'s exhibiting cooperat
ive magnetic properties, have been studied by single crystal X-ray dif
fraction. Each of these materials are ferrimagnets exhibiting ferromag
netic coupling at low temperatures. Herein we summarize the structures
obtained for these compounds and their nu(CN) infrared absorptions. (
C) 1998 Elsevier Science Ltd.