THE STRUCTURE OF SEVERAL SUPRAMOLECULAR MESO-TETRAARRYLPORPHINATOMANGANESE(III) TETRACYANOETHENIDE MAGNETS

Citation
Ej. Brandon et al., THE STRUCTURE OF SEVERAL SUPRAMOLECULAR MESO-TETRAARRYLPORPHINATOMANGANESE(III) TETRACYANOETHENIDE MAGNETS, Materials research bulletin, 1998, pp. 97-107
Citations number
35
Categorie Soggetti
Material Science
Journal title
ISSN journal
00255408
Year of publication
1998
Supplement
S
Pages
97 - 107
Database
ISI
SICI code
0025-5408(1998):<97:TSOSSM>2.0.ZU;2-G
Abstract
Supramolecular structures of several uniform ... D(+)A .D-+A .(-)D(+)A .(-) (D: S = 2 Mporphyrin; A: S = 1/2 TCNE) coordination polymers, wi th the [TCNE] .(-)trans-mu bonded to two Mn(III)'s exhibiting cooperat ive magnetic properties, have been studied by single crystal X-ray dif fraction. Each of these materials are ferrimagnets exhibiting ferromag netic coupling at low temperatures. Herein we summarize the structures obtained for these compounds and their nu(CN) infrared absorptions. ( C) 1998 Elsevier Science Ltd.