DETERMINATION OF THE TRUE FORM OF OVERLAPPING PEAKS, DEFORMED BY THE BASE-LINE IN THE CASE OF STRIPPING VOLTAMMETRY

Authors
STROMBERG AG ROMANENKO SV
Citation
Ag. Stromberg et Sv. Romanenko, DETERMINATION OF THE TRUE FORM OF OVERLAPPING PEAKS, DEFORMED BY THE BASE-LINE IN THE CASE OF STRIPPING VOLTAMMETRY, Fresenius' journal of analytical chemistry, 361(3), 1998, pp. 276-279
Citations number
38
Categorie Soggetti
Chemistry Analytical
Journal title
Fresenius' journal of analytical chemistry → ACNP
ISSN journal
09370633
Volume
361
Issue
3
Year of publication
1998
Pages
276 - 279
Database
ISI
SICI code
0937-0633(1998)361:3<276:DOTTFO>2.0.ZU;2-U
Abstract
A way to determine the form of an analytical signal without accounting of the base line is described. It Is based on subtraction of two peak s. The validity of correction of the base line inclination with the he lp of a linear function is indicated. The ability to determine the tru e form of the analytical signal in case of overlapping signals is prov ed. The approach was applied to define the degree of non-additivity of the analytical signal and the character of change of the peak shape a s a function of concentration.