CATALYTIC TRANSFER HYDROGENATION OF OLEFINS

Authors
DOBROVOLNA Z CERVENY L
Citation
Z. Dobrovolna et L. Cerveny, CATALYTIC TRANSFER HYDROGENATION OF OLEFINS, Research of chemical intermediates, 24(6), 1998, pp. 679-686
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Research of chemical intermediates → ACNP
ISSN journal
09226168
Volume
24
Issue
6
Year of publication
1998
Pages
679 - 686
Database
ISI
SICI code
0922-6168(1998)24:6<679:CTHOO>2.0.ZU;2-W
Abstract
Catalytic transfer hydrogenation with simultaneous isomerization of 1- olefins (C-6 - C-8), 1,3-cyclohexadiene, 1,7-octadiene and cyclohexene using ammonium formate on 3% Pd/C at 20 degrees C in methanol was stu died. The effect of the experimental procedure upon the hydrogenation course was discussed. The effect of applied donor quantity upon the hy drogenation selectivity and individual substrate reactivity was monito red.