A STUDY ON ONE-ELECTRON OXIDATION OF PHENOTHIAZINE-DERIVATIVES BY PIPERIDINE OXOAMMONIUM ION IN SDS MICELLE

Authors
ZHANG HM RUAN XQ GUO QX LIU YC
Citation
Hm. Zhang et al., A STUDY ON ONE-ELECTRON OXIDATION OF PHENOTHIAZINE-DERIVATIVES BY PIPERIDINE OXOAMMONIUM ION IN SDS MICELLE, Research of chemical intermediates, 24(6), 1998, pp. 687-693
Citations number
37
Categorie Soggetti
Chemistry
Journal title
Research of chemical intermediates → ACNP
ISSN journal
09226168
Volume
24
Issue
6
Year of publication
1998
Pages
687 - 693
Database
ISI
SICI code
0922-6168(1998)24:6<687:ASOOOO>2.0.ZU;2-T
Abstract
N-Substituted phenothiazines were oxidized by 2,2,6,6-tetramethy-4-ace tyloxypiperidine oxoammonium hexachloroantimonate (TAPO) to the corres ponding radical cations in sodium dodecyl sulfate (SDS) micellar solut ion. The radical cations of phenothiazine derivatives were generated a nd stabilized by the anionic micelle in aqueous solution. mn electron transfer mechanism has been proposed.