POTASSIUM FLUORIDE ON ALUMINA - CONDENSATION OF 3-METHYL-2-THIONO-4-THIAZOLIDINONE WITH ALDEHYDES - SYNTHESIS OF ALPHA-THIOACRYLIC ACIDS AND PHOSPHONOTHIONOTHIAZOLIDINONES

Authors
VILLEMIN D BENALLOUM A
Citation
D. Villemin et A. Benalloum, POTASSIUM FLUORIDE ON ALUMINA - CONDENSATION OF 3-METHYL-2-THIONO-4-THIAZOLIDINONE WITH ALDEHYDES - SYNTHESIS OF ALPHA-THIOACRYLIC ACIDS AND PHOSPHONOTHIONOTHIAZOLIDINONES, Phosphorus, sulfur and silicon and the related elements, 79(1-4), 1993, pp. 33-41
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
79
Issue
1-4
Year of publication
1993
Pages
33 - 41
Database
ISI
SICI code
1042-6507(1993)79:1-4<33:PFOA-C>2.0.ZU;2-Y
Abstract
3-Methyl-2-thiono-4-thiazolidinone and aromatic aldehydes adsorbed on potassium fluoride on alumina gave under microwave irradiation 5-aryli dene-3-methyl-2-thiono-4-thiazolidinones in 70% to 90% yield. These co mpounds can be cleaved with sodium hydroxide on alumina into alpha-thi olacrylic acids in quasi-quantitative yields. Michael addition of diet hyl phosphite to 5-arylidene-3-methyl-2-thiono-4-thiazolidinone is des cribed for the first time.