Thin films of ZnSe are heteroepitaxially grown on GaAs{111}A, B-(2 x 2
) surfaces. On the GaAs(111)A-(2 x 2) surface ZnSe grows in a biatomic
layer-by-layer mode. Interestingly, at the very initial stage of ZnSe
growth on GaAs(111)A, the growth rate increases and decreases with in
creasing Se to Zn flux ratio and ZnSe film thickness, respectively. On
the other hand,. ZnSe growth on GaAs(111)B-(2 x 2) proceeds in an isl
and mode regardless of the flux ratio. A possible mechanism for the on
set of such different growth modes is discussed. (C) 1998 Elsevier Sci
ence B.V. All rights reserved.