NEW DECONTAMINANTS - OXIDATIVE ELIMINATIO N OF AN YPERITE ANALOG, 2-PHENYL-2'-CHLORODIETHYLSULFIDE, USING POTASSIUM MONOPERSULFATE

Authors
LEBLANC A FOSSET L MAGNAUD G DELMAS G DESGRANGES M SENTENACROUMANOU H LION C CHARVY C MOHRI A
Citation
A. Leblanc et al., NEW DECONTAMINANTS - OXIDATIVE ELIMINATIO N OF AN YPERITE ANALOG, 2-PHENYL-2'-CHLORODIETHYLSULFIDE, USING POTASSIUM MONOPERSULFATE, Phosphorus, sulfur and silicon and the related elements, 79(1-4), 1993, pp. 141-145
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
79
Issue
1-4
Year of publication
1993
Pages
141 - 145
Database
ISI
SICI code
1042-6507(1993)79:1-4<141:ND-OEN>2.0.ZU;2-P
Abstract
The reaction of potassium monopersulfate (CUROX or OXONE) with 2-pheny l 2'-chloro diethylsulfide PhCH2CH2SCH2CH2Cl goes to completion in a v ery short time. The intermediate chlorinated sulfone PhCH2CH2SO2CH2CH2 Cl leads the phenethylvinylsulfone PhCH2CHSO2CH=CH2 by HCl elimination .