A CYCLOMETALATED PD(II) COMPLEX CONTAINING A CYTOSINE MODEL NUCLEOBASE

Authors
NAVARRORANNINGER C MONTERO EI LOPEZSOLERA I MASAGUER JR LIPPERT B
Citation
C. Navarroranninger et al., A CYCLOMETALATED PD(II) COMPLEX CONTAINING A CYTOSINE MODEL NUCLEOBASE, Journal of organometallic chemistry, 558(1-2), 1998, pp. 103-110
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
558
Issue
1-2
Year of publication
1998
Pages
103 - 110
Database
ISI
SICI code
0022-328X(1998)558:1-2<103:ACPCCA>2.0.ZU;2-B
Abstract
The acetate bridges in a cyclometallated, dinuclear complex 3 of Pd(II ) with the 3,8-dinitro- 6-phenylphen anthridine ligand can be substitu ted by the deprotonated model nucleobase 1-methylcytosine to give a do ubly bridged 1-methylcytosinato complex 4. 4 has a folded structure as concluded from H-1 NMR spectroscopy. (C) 1998 Elsevier Science S.A. A ll rights reserved.