SILOXY-SUBSTITUTED TETRAMETHYLCYCLOPENTADIENYL AND INDENYL TRICHLOROTITANIUM COMPLEXES FOR SYNDIOSPECIFIC POLYMERIZATION OF STYRENE

Authors
TIAN GL XU SS ZHANG YQ WANG BQ ZHOU XZ
Citation
Gl. Tian et al., SILOXY-SUBSTITUTED TETRAMETHYLCYCLOPENTADIENYL AND INDENYL TRICHLOROTITANIUM COMPLEXES FOR SYNDIOSPECIFIC POLYMERIZATION OF STYRENE, Journal of organometallic chemistry, 558(1-2), 1998, pp. 231-233
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
558
Issue
1-2
Year of publication
1998
Pages
231 - 233
Database
ISI
SICI code
0022-328X(1998)558:1-2<231:STAIT>2.0.ZU;2-H
Abstract
ta(5)-trimethylsiloxytetramethylcyclopentadienyl)- and (eta(5)-2- trim ethylsiloxyindenyl)trichloro titanium have been synthesized and charac terized. Their catalytic behavior for the polymerization of styrene wa s studied in the presence of methylaluminoxane (MAO) as a cocatalyst. They show only low activity for styrene polymerization. (C) 1998 Elsev ier Science S.A. All rights reserved.