CP2TICL2-CATALYZED PINACOL-TYPE COUPLING OF ALIPHATIC-ALDEHYDES BY USE OF ZINC AND CHLOROSILANE

Authors
HIRAO T HATANO B ASAHARA M MUGURUMA Y OGAWA A
Citation
T. Hirao et al., CP2TICL2-CATALYZED PINACOL-TYPE COUPLING OF ALIPHATIC-ALDEHYDES BY USE OF ZINC AND CHLOROSILANE, Tetrahedron letters, 39(29), 1998, pp. 5247-5248
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
29
Year of publication
1998
Pages
5247 - 5248
Database
ISI
SICI code
0040-4039(1998)39:29<5247:CPCOAB>2.0.ZU;2-4
Abstract
Bis(cyclopentadienyl)titanium dichloride (Cp2TiCl2) exhibits excellent catalytic activity toward the pinacol-type coupling reaction of aliph atic aldehydes with the assistance of zinc powder and chlorosilane. (C ) 1998 Elsevier Science Ltd. All rights reserved.