A 1,3-DIPOLAR CYCLOADDITION ROUTE TO 7-AZANORBORNANES - APPLICATION TO THE SYNTHESIS OF SYN-FACIAL N-BRIDGED POLYNORBORNANES

Authors
BUTLER DN MALPASS JR MARGETIC D RUSSELL RA SUN GX WARRENER RN
Citation
Dn. Butler et al., A 1,3-DIPOLAR CYCLOADDITION ROUTE TO 7-AZANORBORNANES - APPLICATION TO THE SYNTHESIS OF SYN-FACIAL N-BRIDGED POLYNORBORNANES, Synlett, (6), 1998, pp. 588
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
6
Year of publication
1998
Database
ISI
SICI code
0936-5214(1998):6<588:A1CRT7>2.0.ZU;2-T
Abstract
Aziridinocyclobutenes react with electron-deficient or ring-strained a lkenes to produce 7-azanorbornenes in a novel 1,3-dipolar cycloadditio n reaction suitable for BLOCK assembly protocols. Benzo-7-azanorbornad iene and 7-heterobridged analogues react stereoselectively to produce compounds with syn-facial orientation of their bridges.