INTRAMOLECULAR PD CATALYZED CARBOCYCLIZATION REACTIONS WITH PLANAR CHIRAL ARENE TRICARBONYL CHROMIUM COMPLEXES

Authors
CROUSSE B XU LH BERNARDINELLI G KUNDIG EP
Citation
B. Crousse et al., INTRAMOLECULAR PD CATALYZED CARBOCYCLIZATION REACTIONS WITH PLANAR CHIRAL ARENE TRICARBONYL CHROMIUM COMPLEXES, Synlett, (6), 1998, pp. 658
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
6
Year of publication
1998
Database
ISI
SICI code
0936-5214(1998):6<658:IPCCRW>2.0.ZU;2-3
Abstract
ortho-Butenylchlorobenzene tricarbonylchromium complexes undergo intra molecular Pd catalyzed cyclizations (Heck-reactions) without decomplex ation and/or alkene isomerization. The diastereoselectivity of the alk ene carbopalladation is governed by the planar chirality of the comple x.