INFLUENCE OF THE INITIATION SYSTEM COMPOS ITION ON THE TOPOCHEMISTRY OF SUSPENSION POLYMERIZATION OF VINYL-CHLORIDE AND THE POLYMER MORPHOLOGY

Authors
KRONMAN AG SEMCHIKOV YD GROSHEV GL KANAKOV AE
Citation
Ag. Kronman et al., INFLUENCE OF THE INITIATION SYSTEM COMPOS ITION ON THE TOPOCHEMISTRY OF SUSPENSION POLYMERIZATION OF VINYL-CHLORIDE AND THE POLYMER MORPHOLOGY, Vysokomolekularnye soedinenia. Seria A, 39(10), 1997, pp. 1588-1592
Citations number
8
Journal title
Vysokomolekularnye soedinenia. Seria A → ACNP
ISSN journal
05075475
Volume
39
Issue
10
Year of publication
1997
Pages
1588 - 1592
Database
ISI
SICI code
0507-5475(1997)39:10<1588:IOTISC>2.0.ZU;2-Z
Abstract
The regularities of the suspension polymerization of vinyl chloride in the presence of initiation systems were studied. The initiation syste ms consisted of di-2-ethylhexyl peroxydicarbonate in combination with reducing agents (such as phthalimide or alkyl betaine) and alkali meta l persulfate. The morphology of the suspension poly(vinyl chloride) wa s studied by electron microscopy. Correlation between the composition of the initiation system and the polymer grain structure was establish ed.