Cj. Latimer et al., A DISSOCIATIVE PHOTOIONIZATION STUDY OF THE AUTOIONIZATION LIFETIME OF THE LOWEST (1)SIGMA(U) SUPEREXCITED STATE IN HYDROGEN AND DEUTERIUM, Journal of physics. B, Atomic molecular and optical physics, 26(18), 1993, pp. 595-600
The kinetic energy spectra of the fragment protons and deuterons produ
ced in the dissociative photoionization of H-2 and D2 by 30.5 eV photo
ns have been measured. It is shown that the ratio of the proton to deu
teron spectra can provide an experimental estimate of the autoionizing
lifetime of the 1SIGMA(u)(1) superexcited state as a function of inte
rnuclear separation. The experimentally determined lifetimes are signi
ficantly smaller than theoretical predictions.