Dg. Ma et al., BLUE-LIGHT-EMITTING DIODES AND FLAT DISPLAY BASED ON POLY(P-PHENYLENEVINYLENE) COPOLYMERS, Science in China. Series B, Chemistry, life sciences & earth sciences, 41(3), 1998, pp. 272-277
Copolymers containing alternating flexible aliphatic blocks and rigid
poly(p-phenylenevinylene) (PPV) blocks were synthesized and characteri
zed. It was found that the fluorescent intensity increases with increa
sing length of the flexible blocks. Bright blue-light emitting diodes
were fabricated using PPV copolymers as electroluminescent layers. The
devices show 190 cd/m(2) light-emitting brightness at 460 nm and 15 V
rum-on voltage. The effects of oxadiazole derivative PBD and tris(8-h
ydroxyquinoline) aluminum Alq(3) electron-transporting layers on the l
uminance and stability of the devices are discussed.