STUDIES ON ORGANOPHOSPHORUS COMPOUNDS .78. NEW ASPECTS ON THE INDUCEDASYMMETRIC ADDITION OF DIALKYL PHOSPHITE TO ALDIMINES - AN EFFECTIVE SYNTHESIS OF CHIRAL 1-ARYLPHOSPHONOGLYCINE DERIVATIVES

Citation
Cy. Yuan et al., STUDIES ON ORGANOPHOSPHORUS COMPOUNDS .78. NEW ASPECTS ON THE INDUCEDASYMMETRIC ADDITION OF DIALKYL PHOSPHITE TO ALDIMINES - AN EFFECTIVE SYNTHESIS OF CHIRAL 1-ARYLPHOSPHONOGLYCINE DERIVATIVES, Phosphorus, sulfur and silicon and the related elements, 81(1-4), 1993, pp. 27-35
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
10426507
Volume
81
Issue
1-4
Year of publication
1993
Pages
27 - 35
Database
ISI
SICI code
1042-6507(1993)81:1-4<27:SOOC.N>2.0.ZU;2-O
Abstract
Addition of dialkyl phosphites to Schiff bases derived from (R)-2-meth oxy-1-phenylethylamine or (R)-phenylglycine methyl ester afforded (1R, 1'R)-1-arylphosphonoglycine derivatives with moderate to high diaster eoselectivity. The influence of catalysts and solvents and the structu ral effects of the substrates on this stereochemical process were repo rted.