This article shows the existence of a non-uniform stationary measure (
referred to as the w-invariant measure) associated with the space-fill
ing properties of the unstable manifold and characterizing some statis
tical properties of chaotic two-dimensional area-preserving systems. T
he w-invariant measure, which differs from the ergodic measure and is
non-uniform in general, plays a central role in the statistical charac
terization of chaotic fluid mixing systems, since several properties o
f partially mixed structures can be expressed as ensemble averages ove
r the w-invariant measure. A closed-form expression for the w-invarian
t density is obtained for a class of mixing systems topologically conj
ugate with the linear toral automorphism. The physical implications in
the theory of fluid mixing, and in the statistical characterization o
f chaotic Hamiltonian systems, are discussed. (C) 1998 Elsevier Scienc
e B.V. All rights reserved.