A number of new ferroelectric side chain liquid crystal homopolymers d
erived from poly(hydromethylsiloxane), their copolymers with different
mesogens and with poly(dimethylsiloxane) backbones have been prepared
. The transition temperatures of the monomers, homo and copolymers hav
e been determined. The homopolymers exhibit S(C) and N* phases, while
copolymers show only a S(C) phase. A measured spontaneous polarizati
on value of monomer, 9b, is larger than 500 nC cm-2.