OXIDATION OF ALPHA-PINENE BY OH-CENTER-DOT, CL-CENTER-DOT AND CL-2-CENTER-DOT- RADICALS

Citation
T. Kluge et al., OXIDATION OF ALPHA-PINENE BY OH-CENTER-DOT, CL-CENTER-DOT AND CL-2-CENTER-DOT- RADICALS, Journal of radioanalytical and nuclear chemistry, 232(1-2), 1998, pp. 103-105
Citations number
5
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Analytical","Nuclear Sciences & Tecnology
ISSN journal
02365731
Volume
232
Issue
1-2
Year of publication
1998
Pages
103 - 105
Database
ISI
SICI code
0236-5731(1998)232:1-2<103:OOABOC>2.0.ZU;2-E
Abstract
The rate constants of the reactions of the radicals OH. and Cl-2(.-) w ith alpha-pinene determined by pulse radiolysis in aqueous solution ar e given. The reaction of Cl-. with alpha-pinene has been studied by la ser photolyis in CCl4 solution. Furthermore, the rate constants of the reactions of the formed organic radicals with oxygen as well as those of the deactivation of all radicals were determined.