T. Akachi et al., SITE OCCUPANCY AND T-C DEGRADATION IN IRON SUBSTITUTED YBA2(CU1-XFEX)(4)O8+DELTA, Physica. C, Superconductivity, 301(3-4), 1998, pp. 315-325
A series of YBa2(Cu1-xFex)(4)O8+delta a samples with x = 0.00625, 0.01
25, 0.01875, 0.025 and 0.05, were synthesized and characterized by res
istance vs, temperature measurements, X-ray diffraction and by Mossbau
er spectroscopy. In order to make the site assignment for the Fe atoms
, a Rietveld refinement of the X-ray spectra was performed and a point
charge calculation of the quadrupole splitting for all the possible o
xygen environments around the two Cu sites was carried out, taking int
o account the two possible ionic states of the iron atoms that occupy
those sites. We found that, for low level iron concentrations, the Fe
atoms occupy only the Cu(1) sites of the structure in a fivefold pyram
idal coordination, with the apical oxygen atom placed along the a-axis
between the double chains of the unit cell. The presence of these ext
ra oxygen atoms in the crystal structure could be related to the rapid
T-c reduction as iron concentration increases. (C) 1998 Published by
Elsevier Science B.V. All rights reserved.