SELECTIVE ONE-POT SYNTHESIS OF SECONDARY AND TERTIARY-AMINES VIA RHODIUM-CATALYZED REDUCTION AND MULTIPLE ALKYLATION OF AROMATIC NITRO-COMPOUNDS UNDER HYDROFORMYLATION CONDITIONS

Authors
RISCHE T EILBRACHT P
Citation
T. Rische et P. Eilbracht, SELECTIVE ONE-POT SYNTHESIS OF SECONDARY AND TERTIARY-AMINES VIA RHODIUM-CATALYZED REDUCTION AND MULTIPLE ALKYLATION OF AROMATIC NITRO-COMPOUNDS UNDER HYDROFORMYLATION CONDITIONS, Tetrahedron, 54(29), 1998, pp. 8441-8450
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
54
Issue
29
Year of publication
1998
Pages
8441 - 8450
Database
ISI
SICI code
0040-4020(1998)54:29<8441:SOSOSA>2.0.ZU;2-3
Abstract
Secondary and tertiary amines are selectively prepared in high yields by a one-pot reduction / multiple alkylation procedure from aromatic n itro compounds with styrenes, cyclic olefins or heterofunctionalised o lefins, carbon monoxide and hydrogen in the presence of [Rh(cod)Cl](2) as catalyst. (C) 1998 Elsevier Science Ltd. All rights reserved.