New contact fill integration schemes were developed for high aspect ra
tio Gb DRAM contact metallization. Integration schemes for both tungst
en-plug contacts and aluminum-plug contacts were studied. For tungsten
-plug contacts, various types of titanium liners and titanium nitride
barriers were investigated and evaluated. These included collimated PV
D (physical vapor deposition) titanium, ion metal plasma (IMP) titaniu
m, and CVD (chemical vapor deposition) titanium liners; plasma enhance
d CVD (PECVD) titanium nitride and plasma enhanced MOCVD (ECVD) titani
um nitride barriers. The electrical results of 0.3 mu m, 5:1 aspect ra
tio (AR) contact structures processed with a TiCl4-based CVD titanium
liner and plasma enhanced CVD titanium nitride barrier show the lowest
and the most tightly distributed contact parametrics. This is attribu
ted to the conformal nature of the CVD process. In addition, the high
titanium-deposition temperature, which leads to a simultaneous titaniu
m silicide formation during the CVD titanium deposition process, may a
lso have attribution to the low contact resistance and diode leakage o
btained. In the case of aluminum-plug contacts, two different types of
titanium nitride barriers (ECVD titanium nitride vs. silane-treated M
OCVD titanium nitride) were evaluated and both showed comparable conta
ct parametrics. (C) 1998 Elsevier Science S.A. All rights reserved.