STRUCTURE OF DIISOBUTYL-1,3-DIMETHOXYPROPANE-O,O')TITANIUM(IV)]

Authors
IISKOLA E PELKONEN A KAKKONEN HJ AHLGREN M PAKKANEN TA PURSIAINEN J
Citation
E. Iiskola et al., STRUCTURE OF DIISOBUTYL-1,3-DIMETHOXYPROPANE-O,O')TITANIUM(IV)], Acta crystallographica. Section C, Crystal structure communications, 49, 1993, pp. 1607-1609
Citations number
18
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
49
Year of publication
1993
Part
9
Pages
1607 - 1609
Database
ISI
SICI code
0108-2701(1993)49:<1607:SOD>2.0.ZU;2-R
Abstract
TiCl4 reacts with (iC4H9)2C(CH2OCH3)2 in n-heptane forming the monomer ic complex [TiCl4(C13H28O2)] which is converted into the oxygen-bridge d dimeric structure [TiCl3(C13H28O2)]2O in the presence of H2O. In the dimeric structure the coordination of each Ti atom is octahedral. The angle between the bridging O atom and the Ti atoms is 163.4 (4)-degre es.