S. Dailey et al., AN EFFICIENT ELECTRON-TRANSPORTING POLYMER FOR LIGHT-EMITTING-DIODES, Journal of physics. Condensed matter, 10(23), 1998, pp. 5171-5178
The efficient operation of polymer light-emitting diodes (LEDs) requir
es balanced injection and transport of electrons and holes. This has s
timulated much research into suitable electron-injecting and transport
ing materials. We report the use of polypyridine as an efficient elect
ron-transporting polymer. We have achieved much-improved LED performan
ce by incorporating polypyridine as an electron-transporting layer in
a poly(p-phenylene vinylene) (PPV) LED and optimizing layer thicknesse
s to balance transport of electrons and holes. The external quantum ef
ficiency of these LEDs is 0.25%, 60 times greater than similar devices
without the electron-transporting layer.