STRUCTURE OF 3-EPIRYANODOL - A HEPTAHYDRO DITERPENE

Authors
MICHEL AG DROUIN M
Citation
Ag. Michel et M. Drouin, STRUCTURE OF 3-EPIRYANODOL - A HEPTAHYDRO DITERPENE, Acta crystallographica. Section C, Crystal structure communications, 49, 1993, pp. 1685-1688
Citations number
9
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
49
Year of publication
1993
Part
9
Pages
1685 - 1688
Database
ISI
SICI code
0108-2701(1993)49:<1685:SO3-AH>2.0.ZU;2-F
Abstract
As part of an investigation of structure-activity relationships of rya noids, the crystal structure of 3-epiryanodol was carried out in order to confirm its stereochemistry Ryanodol has 11 asymmetric C atoms. Th e C3 atom, which has R stereochemistry in the natural product, was inv erted to the S stereochemistry to give this 3-epimer of ryanodol. The compound makes three inter- and four intramolecular hydrogen bonds.