A new C,O-diglucosylated oxanthrone, named littoraloside, has been iso
lated from the leaf exudate of Aloe littoralis, along with the previou
sly reported compounds, littoraloin, deacetyllittoraloin and 10-hydrox
yaloin B. The structure, including the stereochemistry of littoralosid
e was established on the basis of spectral analyses, as well as by con
version to deacetyllittoraloin and to 10-hydroxyaloin B by enzymatic a
nd acid catalyzed hydrolysis, respectively. (C) 1998 Published by Else
vier Science Ltd. All rights reserved.