SYNTHESIS OF A NEW CHROMOGENIC REAGENT, 1-(P-AZOPHENYL)-3-(2-THIAZOL)TRIAZENE, AND ITS APPLICATION TO DETERMINATION OF ZINC(II)

Authors
ZHU YR JIANG WQ WU GH JIN G
Citation
Yr. Zhu et al., SYNTHESIS OF A NEW CHROMOGENIC REAGENT, 1-(P-AZOPHENYL)-3-(2-THIAZOL)TRIAZENE, AND ITS APPLICATION TO DETERMINATION OF ZINC(II), Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 37(5), 1998, pp. 466-468
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical
ISSN journal
03764710 → ACNP
Volume
37
Issue
5
Year of publication
1998
Pages
466 - 468
Database
ISI
SICI code
0376-4710(1998)37:5<466:SOANCR>2.0.ZU;2-Y
Abstract
Synthesis and characterization of a new chromogenic reagent, 1-(p-azop henyl)-3-(2-thiazol)triazene(APT are described. The reagent has been u sed for spectrophotometric determination of zinc(II). APTT forms a red colored complex with zinc(II) in alkaline medium in the presence of T riton X-100. The optimum conditions for the colour reaction have been described. The molar absorptivity of the complex is 9.6 x 10(4) l.mol( 1) cm(-1) at 545 nm. Beer's law is obeyed over the range 0 - 24 mu g/2 5ml Zn(II). Interference due to several ions has been studied. The rec ommended method has been applied to the determination of zinc(II) in a luminum alloys.