MOLYBDENUM(V) CHLOROMONOPHOSPHATES WITH A LAYER STRUCTURE - AMOOPO(4)CL (A = K, RB)

Authors
BOREL MM LECLAIRE A CHARDON J PROVOST J RAVEAU B
Citation
Mm. Borel et al., MOLYBDENUM(V) CHLOROMONOPHOSPHATES WITH A LAYER STRUCTURE - AMOOPO(4)CL (A = K, RB), Journal of solid state chemistry (Print), 137(2), 1998, pp. 214-217
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Journal of solid state chemistry (Print) → ACNP
ISSN journal
00224596
Volume
137
Issue
2
Year of publication
1998
Pages
214 - 217
Database
ISI
SICI code
0022-4596(1998)137:2<214:MCWALS>2.0.ZU;2-9
Abstract
Two new pentavalent molybdenum chloromonophosphates, KMoOPO4Cl and RbM oOPO4Cl, have been synthesized. They crystallize in the p4/nmm space g roup with a = b = 6.4340(5) and c = 7.2715(9) Angstrom for the potassi um compound and a = b = 6.4551(8) and c = 7.4612(8) Angstrom for the r ubidium compound. Their original structure consists of [MoPO5Cl](infin ity), layers parallel to (001), whose cohesion is ensured by K+ or Rb ions. The chloride ions and the alkali metal cations form a puckered rock salt layer. (C) 1998 Academic Press.