NONLINEAR EFFECTS AS INDICATORS IN THE TUNING OF ASYMMETRIC CATALYSTS

Authors
BRUNEL JM LUUKAS TO KAGAN HB
Citation
Jm. Brunel et al., NONLINEAR EFFECTS AS INDICATORS IN THE TUNING OF ASYMMETRIC CATALYSTS, Tetrahedron : asymmetry, 9(11), 1998, pp. 1941-1946
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
9
Issue
11
Year of publication
1998
Pages
1941 - 1946
Database
ISI
SICI code
0957-4166(1998)9:11<1941:NEAIIT>2.0.ZU;2-H
Abstract
Nonlinear effects (NLEs) have been used as a new tool to characterize the various modifications of a chiral titanium complex used in stoichi ometric or catalytic mode in asymmetric sulfoxidation by cumyl hydrope roxide. Spectacular changes from (+)- to (-)-NLEs were observed for mi nor modifications of the experimental conditions. (C) 1998 Elsevier Sc ience Ltd. All rights reserved.