QUANTUM-CHEMICAL STUDY ON FORMATION OF THIONITROSO COMPOUNDS FROM N-CHLORO-SULFENYL-N-TRIMETHYLSILYL AMINES

Authors
PENKOVSKY VV SHERMOLOVITCH YG
Citation
Vv. Penkovsky et Yg. Shermolovitch, QUANTUM-CHEMICAL STUDY ON FORMATION OF THIONITROSO COMPOUNDS FROM N-CHLORO-SULFENYL-N-TRIMETHYLSILYL AMINES, Phosphorus, sulfur and silicon and the related elements, 80(1-4), 1993, pp. 255-258
Citations number
3
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
80
Issue
1-4
Year of publication
1993
Pages
255 - 258
Database
ISI
SICI code
1042-6507(1993)80:1-4<255:QSOFOT>2.0.ZU;2-N
Abstract
The MNDO quantum-chemical calculations revealed that the N-chlorosulfe nyl-N-trimethylsilyl amine decomposition scheme may be described as th e S-Cl bond weakening and the subsequent trimethylsilyl group transfer to the chlorine atom, with the activation barrier of 260-294 kJ/mol.