The effect of isotacticity of polypropylene(PP) on its radiation stabi
lity has been investigated in the present work. It was found that (1)
The G value of Ha and CH4 is smaller if isotacticity of PP is higher;
(2) It is easier to be crosslinked by radiation for the PP with higher
isotacticity; (3) The shape of DSC peak changes smaller after irradia
tion for PP with higher isotacticity. These results have been explaine
d by the measurement of C-13-NMR and small angle X-ray scattering.