SYNTHESES OF NOVEL CHIRAL 2,5-DIALKYL-7-AZABICYCLO[2.2.1]HEPTANES AND2,5-DIALKYL-7-THIOBICYCLO[2.2.1]HEPTANES

Authors
XIAO DM ZHANG ZG JIANG QZ ZHANG XM
Citation
Dm. Xiao et al., SYNTHESES OF NOVEL CHIRAL 2,5-DIALKYL-7-AZABICYCLO[2.2.1]HEPTANES AND2,5-DIALKYL-7-THIOBICYCLO[2.2.1]HEPTANES, Tetrahedron letters, 39(30), 1998, pp. 5331-5334
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
30
Year of publication
1998
Pages
5331 - 5334
Database
ISI
SICI code
0040-4039(1998)39:30<5331:SONC2A>2.0.ZU;2-O
Abstract
New C-2-symmetric chiral amines with a rigid bicyclic framework have b een synthesized via hydrogenation of monoazides catalyzed by 5% Pd/C i n methanol. Enantiomerically pure 2,5-dialkyl-7-thiobicyclo[2.2.1]hept anes were made from readily available materials. (C) 1998 Elsevier Sci ence Ltd. All rights reserved.