REGIOSPECIFICITY AND STEREOSPECIFICITY IN RADICAL CASCADE CYCLIZATIONS OF TMS-ALKYNE CONTAINING ALLYL BROMOMETHYLDIMETHYLSILYL ETHERS

Authors
BELVAL F CHAVIS C FRUCHIER A MONTERO JL LUCAS M
Citation
F. Belval et al., REGIOSPECIFICITY AND STEREOSPECIFICITY IN RADICAL CASCADE CYCLIZATIONS OF TMS-ALKYNE CONTAINING ALLYL BROMOMETHYLDIMETHYLSILYL ETHERS, Tetrahedron letters, 39(30), 1998, pp. 5367-5368
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
30
Year of publication
1998
Pages
5367 - 5368
Database
ISI
SICI code
0040-4039(1998)39:30<5367:RASIRC>2.0.ZU;2-Z
Abstract
Tandem radical cyclization of (E) and (Z) TMS-homopropargyl allyl brom omethyl-dimethylsilyl ethers is reported to provide an all-cis substit uted vinylcyclopentanol 5. Regio- and stereospecificity are discussed. (C) 1998 Elsevier Science Ltd. All rights reserved.