DISPARITY IN THE TANDEM EPOXIDE ALLYLIC ALCOHOL [1,2] [2,3]-WITTIG REARRANGEMENT OF CIS-1-BENZYLOXY-3,4-EPOXYCYCLOPENTANE AND TRANS-1-BENZYLOXY-3,4-EPOXYCYCLOPENTANE/

Authors
BROOKES PC MURPHY PJ SOMMER K HIBBS DE HURSTHOUSE MB MALIK KMA
Citation
Pc. Brookes et al., DISPARITY IN THE TANDEM EPOXIDE ALLYLIC ALCOHOL [1,2] [2,3]-WITTIG REARRANGEMENT OF CIS-1-BENZYLOXY-3,4-EPOXYCYCLOPENTANE AND TRANS-1-BENZYLOXY-3,4-EPOXYCYCLOPENTANE/, Journal of the Chemical Society. Perkin transactions. I (Print), (12), 1998, pp. 1899-1901
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I (Print) → ACNP
ISSN journal
0300922X
Issue
12
Year of publication
1998
Pages
1899 - 1901
Database
ISI
SICI code
0300-922X(1998):12<1899:DITTEA>2.0.ZU;2-E
Abstract
The influence of the relative stereochemistry of the epoxide and benzy loxy functionalities present in cis-1 and trans-1-benzyloxy-3,4-epoxyc yclopentane 3 on the tandem epoxide-allylic alcohol-[1,2]/[2,3]-Wittig rearrangement has been studied, together with the Wittig rearrangemen t of the intermediate alcohols 2 and 4.