A. Ohta et al., THE DESIGN OF AIR-HOLES IN BUTTON TYPE OF ZINC-AIR BATTERIES - II - SIMULATION OF GAS-FLOWS BY AIR-HOLES, Denki Kagaku Oyobi Kogyo Butsuri Kagaku, 66(4), 1998, pp. 425-431
We have introduced a new concept of gas permeability of air holes, so
that we can obtain suitable design guide of air holes in zinc-air batt
eries. In addition to that, we simulated gas Bow through based on hydr
odynamics and conducted several experiments. We compared two experimen
tal results and concluded as follows. (1) Gas permeability is not prop
ortional to the area of air holes but is proportional to the total cir
cumferential length of air holes. For the same area of air holes, perm
eabilities of both oxygen and water vapor are higher with increased nu
mber of air holes with large area. hen over two air holes exist, distr
ibution of oxygen concentration at the electrode surface becomes unifo
rm. (2) When the ration of circumferential length vs. hole diameter is
below 0.2, no significant difference was observed between permeabilit
ies of oxygen and water vapor. These conclusion were found to be usefu
l as guideline of the design air holes.