XPS measurements of the electron binding energy are made for thr eleme
nts Zr, Y, Fe, and O at different depths to understand the effect of o
xygen ion bombardment on the interface between a ZrO2-Y2O3 film and an
Fe substrate. The results show that (FeZr)O1+x (x = 1- < 2) is formed
at the interface as a result of the bombardment and reaction of depos
iting atoms and ions. The AES profile shows a broad transient region a
bout 40 nm wide. Carbon contamination, a result of residual gases in t
he chamber during r.f. magnetron sputter deposition, is also discussed
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