ASSEMBLY OF A POROUS 3-DIMENSIONAL COORDINATION POLYMER - CRYSTAL-STRUCTURE OF ([LA-2(ADIPATE)(3)(H2O)(4)]6H(2)O)(N)

Authors
KIRITSIS V MICHAELIDES A SKOULIKA S GOLHEN S OUAHAB L
Citation
V. Kiritsis et al., ASSEMBLY OF A POROUS 3-DIMENSIONAL COORDINATION POLYMER - CRYSTAL-STRUCTURE OF ([LA-2(ADIPATE)(3)(H2O)(4)]6H(2)O)(N), Inorganic chemistry, 37(13), 1998, pp. 3407
Citations number
35
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
37
Issue
13
Year of publication
1998
Database
ISI
SICI code
0020-1669(1998)37:13<3407:AOAP3C>2.0.ZU;2-8
Abstract
The structure and dehydration behavior of the porous 3D coordination p olymer {[La-2(adipate)(3)(H2O)(4)]6H(2)O}(n) are described. Each La3is coordinated by nine oxygen atoms belonging to five carboxylate liga nds and to two water molecules. Large infinite interconnected channels filled with hydrogen-bonded water molecules are formed in the structu re. Upon heating, this compound transforms reversibly into a nonporous lower hydrate.