POLYNUCLEAR AGGREGATION OF MANGANESE DICHLORIDE. SYNTHESES, PROPERTIES, AND STRUCTURES OF POLYMERIC [MNCL2(THF)(1.6)](INFINITY), DIMERIC [(THF)(4)MG(MU-CL)(2)MNCL2], AND IONIC )(4)][MG(H2O)(4)(THF)(2)][MNCL4](2)CENTER-DOT-2THF COMPOUNDS

Authors
SOBOTA P UTKO J JERZYKIEWICZ LB
Citation
P. Sobota et al., POLYNUCLEAR AGGREGATION OF MANGANESE DICHLORIDE. SYNTHESES, PROPERTIES, AND STRUCTURES OF POLYMERIC [MNCL2(THF)(1.6)](INFINITY), DIMERIC [(THF)(4)MG(MU-CL)(2)MNCL2], AND IONIC )(4)][MG(H2O)(4)(THF)(2)][MNCL4](2)CENTER-DOT-2THF COMPOUNDS, Inorganic chemistry, 37(13), 1998, pp. 3428
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
37
Issue
13
Year of publication
1998
Database
ISI
SICI code
0020-1669(1998)37:13<3428:PAOMDS>2.0.ZU;2-2
Abstract
The crystallization of MnCl2 in tetrahydrofuran results in the formati on of polymeric [MnCl2(THF)(1.6)] (1) with an unexpected structure. Th is species represents the first crystallographically defined example o f tetranuclear [Mn-4(mu(3)-Cl)(2)(mu(2)-Cl)(4)Cl-2(THF)(6)] units link ed by MnCl2(THF)(2) moieties. Our observations highlight the importanc e of the M4X6 core present in 1 as a component of cl-olefin polymeriza tion catalysts.