SYNTHESIS AND RUTILELIKE STRUCTURE OF [CD(TCM)(HMT)(H2O)](TCM) (TCM(-) = TRICYANOMETHANIDE, C(CN)(3)(-) HMT = HEXAMETHYLENETETRAMINE)

Authors
BATTEN SR HOSKINS BF ROBSON R
Citation
Sr. Batten et al., SYNTHESIS AND RUTILELIKE STRUCTURE OF [CD(TCM)(HMT)(H2O)](TCM) (TCM(-) = TRICYANOMETHANIDE, C(CN)(3)(-) HMT = HEXAMETHYLENETETRAMINE), Inorganic chemistry, 37(13), 1998, pp. 3432
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
37
Issue
13
Year of publication
1998
Database
ISI
SICI code
0020-1669(1998)37:13<3432:SARSO[>2.0.ZU;2-H
Abstract
The three-dimensional coordination polymer [Cd(tcm)(hmt)(H2O)](tcm) (t cm(-) = tricyanomethanide, C(CN)(3)(-); hmt = hexamethylenetetramine) has a rutilelike topology, with octahedral centers (cadmium atoms) and trigonal centers (hmt ligands and half the tcm anions) in the ratio 1 :2. One of the connections of the three-connecting hmt ligands is a hy drogen-bonding interaction with coordinated water ligands.