SMALL-ANGLE SCATTERING OF POLARIZED-LIGHT - VI - SPHERE DOUBLETS AT REST AND DURING SHEAR

Citation
J. Dubois et al., SMALL-ANGLE SCATTERING OF POLARIZED-LIGHT - VI - SPHERE DOUBLETS AT REST AND DURING SHEAR, Journal of polymer science. Part B, Polymer physics, 36(11), 1998, pp. 2005-2013
Citations number
18
Categorie Soggetti
Polymer Sciences
ISSN journal
08876266
Volume
36
Issue
11
Year of publication
1998
Pages
2005 - 2013
Database
ISI
SICI code
0887-6266(1998)36:11<2005:SSOP-V>2.0.ZU;2-G
Abstract
The polarized or depolarized light scattering by well-defined monodisp ersed sphere doublets is investigated. ?Two configurations of doublets are studied. In the first (at rest) the doublets are randomly oriente d in a plane, in the second the doublets are oriented in a preferred d irection. This is achieved by submitting a suspension of doublets to a shear flow. The scattering patterns are compared to two theoretical p redictions based on simplified geometries. In the first approach, the doublet is approximated by two interpenetrating spheres scattering ind ependently, whereas in the second, an ellipsoid geometry is used. A go od qualitative comparison is obtained. However, the RV and VH patterns of a randomly dispersed suspension are not similar. The observation o f the flow of a doublet suspension in shear shows that the doublets ar e spiraling around the vorticity axis. (C) 1998 John Wiley & Sons, Inc .