J. Dubois et al., SMALL-ANGLE SCATTERING OF POLARIZED-LIGHT - VI - SPHERE DOUBLETS AT REST AND DURING SHEAR, Journal of polymer science. Part B, Polymer physics, 36(11), 1998, pp. 2005-2013
The polarized or depolarized light scattering by well-defined monodisp
ersed sphere doublets is investigated. ?Two configurations of doublets
are studied. In the first (at rest) the doublets are randomly oriente
d in a plane, in the second the doublets are oriented in a preferred d
irection. This is achieved by submitting a suspension of doublets to a
shear flow. The scattering patterns are compared to two theoretical p
redictions based on simplified geometries. In the first approach, the
doublet is approximated by two interpenetrating spheres scattering ind
ependently, whereas in the second, an ellipsoid geometry is used. A go
od qualitative comparison is obtained. However, the RV and VH patterns
of a randomly dispersed suspension are not similar. The observation o
f the flow of a doublet suspension in shear shows that the doublets ar
e spiraling around the vorticity axis. (C) 1998 John Wiley & Sons, Inc
.