PREPARATION OF A MONOMERIC ALUMINUM-DIAZABUTADIENE COMPLEX VIA AN OXIDATIVE ADDITION-REACTION

Authors
COWLEY AH GORDEN JD ABERNETHY CD CLYBURNE JAC MCBURNETT BG
Citation
Ah. Cowley et al., PREPARATION OF A MONOMERIC ALUMINUM-DIAZABUTADIENE COMPLEX VIA AN OXIDATIVE ADDITION-REACTION, Journal of the Chemical Society. Dalton transactions, (12), 1998, pp. 1937-1938
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
12
Year of publication
1998
Pages
1937 - 1938
Database
ISI
SICI code
0300-9246(1998):12<1937:POAMAC>2.0.ZU;2-P
Abstract
Oxidative addition of MesN=CH-CH=NMes (Mes = mesityl) to the aluminium (I) tetramer, [Al(C5Me5)](4), results in the monomeric aluminium(III) derivative, [(eta(5)-C5Me5)AIN(Mes)CH=CHN(Mes)], which has been charac terised by X-ray crystallography.