3RD PHASE-FORMATION IN EXTRACTION OF THORIUM NITRATE BY MIXTURES OF TRIALKYL PHOSPHATES

Citation
Tg. Srinivasan et al., 3RD PHASE-FORMATION IN EXTRACTION OF THORIUM NITRATE BY MIXTURES OF TRIALKYL PHOSPHATES, Solvent extraction and ion exchange, 16(4), 1998, pp. 1001-1011
Citations number
16
Categorie Soggetti
Chemistry
ISSN journal
07366299
Volume
16
Issue
4
Year of publication
1998
Pages
1001 - 1011
Database
ISI
SICI code
0736-6299(1998)16:4<1001:3PIEOT>2.0.ZU;2-W
Abstract
This paper reports the results of the studies on third phase formation during the extraction of thorium nitrate from zero free acidity solut ions by mixtures of trialkyl phosphates. The phosphates used are tri n -butyl phosphate(TBP), triiso butyl phosphate(TiBP), tri sec butyl pho sphate (TsBP) and tri n-amyl phosphate(TAP). The results indicate that small additions of a homologous phosphate can alter the Limiting Orga nic Concentration (LOC) above which the third phase formation takes pl ace and thus can be advantageously utilised. Use of mixtures of the tr ialkyl phosphates as extractant can thus obviate the need for adding m odifiers such as alcohols to the organic phase for avoiding third phas e formation.